Efficient Synthesis of "Star-like" Surfactants via "Click Chemistry" [3+2] Copper (I)-catalyzed Cycloaddition

Virginie Neto; Robert Granet; Pierre Krausz; Grahame Mackenzie

doi:10.1080/07328300802105365

Article dans une revue

Efficient Synthesis of "Star-like" Surfactants via "Click Chemistry" [3+2] Copper (I)-catalyzed Cycloaddition

Virginie Neto ¹ Robert Granet ¹ Pierre Krausz ¹ Grahame Mackenzie

1 LCSN - Laboratoire de Chimie des Substances Naturelles

Abstract : We report an efficient synthesis of tetra‐ and hexa‐substituted carbohydrate‐coated compounds, which we have named "star‐like" surfactants, starting from either α‐methylglucose or myo‐inositol as a central core. The synthesis explores a new approach to such multipolar compounds using [3+2] copper (I)‐catalyzed cycloadditions to attach the respective building blocks.

Keywords : Click chemistry Surfactant Carbohydrate "Click chemistry"

Type de document :

Article dans une revue

Domaine :

Chimie / Chimie organique

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https://hal-unilim.archives-ouvertes.fr/hal-00686426
Contributeur : Françoise Merigaud <>
Soumis le : mardi 10 avril 2012 - 11:20:45
Dernière modification le : mardi 20 mars 2018 - 16:36:41

Efficient Synthesis of "Star-like" Surfactants via "Click Chemistry" [3+2] Copper (I)-catalyzed Cycloaddition

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Efficient Synthesis of "Star-like" Surfactants via "Click Chemistry" [3+2] Copper (I)-catalyzed Cycloaddition

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