 |
Article dans une revue
Iodine-catalyzed one-pot synthesis of unsymmetrical meso-substituted porphyrins
Abstract : The wide range use of 5-(4-nitrophenyl)-10,15,20-triphenylporphyrin is well established, but its synthesis requires two steps and is not very practical. This article describes an iodine-catalyzed one-pot synthesis of this unsymmetrical porphyrin that uses commercial reagents and reactants as such, without prior distillation. Unsymmetrical mono functionalized porphyrins with various functional groups have also been obtained to validate this method. The influence of electronic effects of functional groups (donor or acceptor) has also been studied.
https://hal-unilim.archives-ouvertes.fr/hal-00697387
Contributeur : Claire Douady Connectez-vous pour contacter le contributeur
Soumis le : mardi 15 mai 2012 - 11:32:49
Dernière modification le : mercredi 20 octobre 2021 - 01:31:03
Contributeur : Claire Douady Connectez-vous pour contacter le contributeur
Soumis le : mardi 15 mai 2012 - 11:32:49
Dernière modification le : mercredi 20 octobre 2021 - 01:31:03
