Photonic crystal fibres as efficient separation component in capillary electrophoresis

Matias Calcerrada (1) , Philippe Roy (2) , Carmen García-Ruiz (3) , Miguel Gonzalez-Herraez (4)

1 University of Alcalá / Department of Analytical Chemistry, Physical-Chemistry and Chemical Engineering
2 XLIM-PHOT - Photonique Fibre et Sources Cohérentes
3 University of Alcalá / Department of Analytical Chemistry, Physical-Chemistry and Chemical
4 Department of Electronics, University of Alcala

Telecommunication developments are leading to original and new fibre designs which indeed are being used in a huge variety of fields. In this manuscript we show that Photonic Crystal Fibres (PCFs) can be used as efficient chemical separation devices in commercial capillary electrophoresis (CE) equipment. A comparison of conventional capillaries, PCFs and new devices inspired on PCFs named Smart Micro-Structured Capillaries (SMSCs) is made. Results showed the usefulness and efficiency of these physical supports in CE through the detection of fluorescein. In addition, some considerations to take into account for SMSCs manufacturing are discussed. Further work should allow coupling the separation advantages achieved by these elements with the wide variety of detection techniques available in fibre-optics.

Mots clés: Capillary electrophoresis; Photonic crystal fibres; Laser induced fluorescence; Chemical sensing; Micro-structure; Bundle of capillaries

Domaines: Physique [physics]; Physique [physics]; Optique [physics.optics]

Matias Calcerrada, Philippe Roy, Carmen García-Ruiz, Miguel Gonzalez-Herraez. Photonic crystal fibres as efficient separation component in capillary electrophoresis. Sensors and Actuators B: Chemical, 2014, 191, pp.264. ⟨10.1016/j.snb.2013.09.087⟩. ⟨hal-00912941⟩