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Article dans une revue

Local electrooptic effect of the SiC large-sized nanocrystallites incorporated in polymer matrices

Abstract : Linear electro-optical effect (LEO) is experimentally demonstrated in large-sized (10 and 30 nm) silicon carbide nanocrystallites (nc-SiC) incorporated in poly(N-vinylcarbazole) (PVK) blended with coumarine (MK). By using the angle-dependent polarimetric method at λprobe=694 nm, in both static and photoinduced regimes, we have shown that embedding the nc-SiC within polymer host matrices gives rise to an enhancement of the LEO effective parameters up to 1.325 pm/V. The absence of these phenomena in the separate components--i.e., pure wurtzite-like SiC crystals as well as the organic matrices--suggests that the observed local electro-optical response is intimately driven by the interfacial hyperpolarizabilities appearing between the nc-SiC and the surrounding organic matrix.
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https://hal-unilim.archives-ouvertes.fr/hal-00916064
Contributeur : Johann Bouclé <>
Soumis le : lundi 9 décembre 2013 - 16:49:16
Dernière modification le : mercredi 18 décembre 2019 - 10:56:01

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Johann Bouclé, Abdelhadi Kassiba, J. Emery, I.V. Kityk, Malgorzata Makowska-Janusik, et al.. Local electrooptic effect of the SiC large-sized nanocrystallites incorporated in polymer matrices. Physics Letters A, Elsevier, 2002, 302, pp.196-202. ⟨10.1016/S0375-9601(02)00965-9⟩. ⟨hal-00916064⟩

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