Crosslinked cellulose developed by CuAAC, a route to new materials

Abstract : This work deals with a novel and simple approach of cellulose reticulation using the Huisgen 1,3-dipolar cycloaddition, also known as a 'click chemistry' reaction, catalysed by copper and developed by Sharpless. This reaction is carried out by the addition of a true alkyne and an azide to form a triazole ring connecting the two polysaccharide chains. The addition of two different functions will allow us to control the crosslinking reaction, to avoid intra-chain reactions and thus to promote the creation of an enhanced three-dimensional network. Azidodeoxycellulose was obtained with a DS of 1.5 from tosyl cellulose. The propargylation reaction in aqueous media leading to propargylcellulose with a DS of 1.3. CuAAC reaction was performed between azidodeoxycellulose and propargylcellulose in a DMSO/H(2)O system using CuSO(4), 5H(2)O/sodium ascorbate as catalytic system. The modified cellulose products were analysed by infrared, NMR and X-ray photoelectron spectroscopies and resulting material was analysed using scanning electron microscopy (SEM)
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https://hal-unilim.archives-ouvertes.fr/hal-00935707
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Soumis le : jeudi 23 janvier 2014 - 21:06:27
Dernière modification le : mardi 19 mars 2019 - 13:26:04

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Pierre-Antoine Faugeras, François Brouillette, Rachida Zerrouki. Crosslinked cellulose developed by CuAAC, a route to new materials. Carbohydrate Research, Elsevier, 2012, 356, pp.247-51. ⟨10.1016/j.carres.2011.10.028⟩. ⟨hal-00935707⟩

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