Phase transformation of Ca4[Al6O12]SO4 and its disordered crystal structure at 1073K

D. Kurokawa; S. Takeda; Maggy Colas; T. Asaka; Philippe Thomas; K. Fukuda

doi:10.1016/j.jssc.2014.03.040

Phase transformation of Ca4[Al6O12]SO4 and its disordered crystal structure at 1073K

D. Kurokawa ¹ S. Takeda ¹ Maggy Colas ² T. Asaka ¹ Philippe Thomas ² K. Fukuda ^{1, *}

* Auteur correspondant

1 Nagoya Institute of Technology - NIT (JAPAN)

2 SPCTS-AXE3 - Axe 3 : organisation structurale multiéchelle des matériaux

SPCTS - Science des Procédés Céramiques et de Traitements de Surface

Abstract : The phase transformation of Ca4[Al6O12]SO4 and the crystal structure of its high-temperature phase were investigated by differential thermal analysis temperature-dependent Raman spectroscopy and high- temperature X-ray powder diffraction( CuKα1). We determined the starting temperature of the orthorhombic-to-cubic transformation during heating (¼711K) and that of the reverse transformation during cooling (¼742K). The thermal hysteresis was negative (¼ 31K), suggesting the thermoelas- ticity of the transformation. The space group of the high temperature phase is I43m with the unit-cell dimensions of a¼0.92426(2) nm and V¼0.78955(2) nm3 (Z¼2) at 1073K. The initial structural model was derived by the direct methods and further refined by the Rietveld method. The final structural model showed the orientational disordering of SO4 tetrahedra. The maximum-entropy method-based pattern fitting method was used to confirm the validity of the split-atom model , in which conventional structure bias caused by assuming intensity partitioning was minimized. At around the transformation temperature during heating, the vibrational spectra, corresponding to the Raman-activeSO4 internal stretching mode, showed the continuous and gradual change in the slope of fullwidth at halfmaximum versus temperature curve. This strongly suggests that the orthorhombic-to-cubic phase transformation would be principally accompanied by the statistic al disordering in orientation of the SO4 tetrahedra, without distinct dynamical reorientation.

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Article dans une revue

Domaine :

Chimie / Matériaux

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https://hal-unilim.archives-ouvertes.fr/hal-01044529
Contributeur : Philippe Thomas <>
Soumis le : mercredi 23 juillet 2014 - 16:25:27
Dernière modification le : mercredi 14 février 2018 - 16:21:45

Phase transformation of Ca4[Al6O12]SO4 and its disordered crystal structure at 1073K

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Phase transformation of Ca4[Al6O12]SO4 and its disordered crystal structure at 1073K

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