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Oxygen semi-permeation properties of La 1− x Sr x FeO 3−δ perovskite membranes under high oxygen gradient

Eva Deronzier 1 Thierry Chartier 1 Pierre-Marie Geffroy 1
1 IRCER-AXE1 - IRCER - Axe 1 : procédés céramiques
IRCER - Institut de Recherche sur les CERamiques : AXE1
Abstract : This work is focused on the evaluation of oxygen semi-permeation and electrochemical performances under high oxygen gradient of free cobalt perovskite membrane materials; La 1− x Sr x FeO 3−δ perovskite. For a better understanding of oxygen transport through La 1− x Sr x FeO 3−δ perovskite membranes, the oxygen diffusion, oxygen incorporation, and desorption coefficients were determined under high oxygen gradient in relation to the temperature for La 1− x Sr x FeO 3−δ (with x = 0.1, 0.3, 0.5, and 0.7) by a specific method based on oxygen semi-permeation. The best electrochemical performances were obtained for La 0.3 Sr 0.7 FeO 3−δ (LSF37) and La 0.5 Sr 0.5 FeO 3−δ (LSF55) perovskite membranes with oxygen fluxes of 1.7 × 10 −3 and 1.2 × 10 −3 mol/m 2 s at 900 °C, respectively. The oxygen incorporation and desorption coefficients of LSF55 were two times lower than those of LSF37 and similar to those of La 0.5 Sr 0.5 Fe 0.7 Ga 0.3 O 3−δ . The values of these coefficients are discussed and compared with the data reported in the literature by isotopic exchange for the similar material compositions.
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https://hal-unilim.archives-ouvertes.fr/hal-03219398
Contributeur : Beatrice Derory <>
Soumis le : jeudi 6 mai 2021 - 13:37:55
Dernière modification le : vendredi 7 mai 2021 - 03:22:08

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Eva Deronzier, Thierry Chartier, Pierre-Marie Geffroy. Oxygen semi-permeation properties of La 1− x Sr x FeO 3−δ perovskite membranes under high oxygen gradient. Journal of Materials Research, Cambridge University Press (CUP), 2020, 35 (18), pp.2506-2515. ⟨10.1557/jmr.2020.230⟩. ⟨hal-03219398⟩

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