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Glass Structures and Linea/Nonlinear Optical Properties of Ag2O-doped TeO2 glasses

y. Kasuya 1 T. Suhara 1 T. Hayakawa 1, * Philippe Thomas 2 M. Nogami 1 
* Auteur correspondant
2 SPCTS-AXE3 - Axe 3 : organisation structurale multiéchelle des matériaux
SPCTS - Science des Procédés Céramiques et de Traitements de Surface
Abstract : A family of TeO2-based glasses is known to have high third-order nonlinear properties and expected as nonlinear optical devices. In the present study, we fabricated Ag2O-TeO2 and Ag2O-Nb2O5-TeO2 glasses, and estimated their structures and linear/nonlinear optical properties. The main results showed that the absorption-edge of the glasses was shifted to longer wavelength side with increasing Ag2O content. By Raman spectroscopy, it was found that an increase in Ag2O content promoted to change TeO4 to TeO3/TeO3+1 units. X-ray photoelectron spectroscopy (XPS) revealed the presence of an electronic state of Ag2+ ions, which was supposed to have a large influence on the absorption-edge wavelength. In Ag2O-Nb2O5-TeO2 glass system, the third-order nonlinear susceptibility c (3) increased with increasing Ag2O content at the expense of Nb2O5 content
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Soumis le : mercredi 23 juillet 2014 - 16:02:09
Dernière modification le : samedi 26 mars 2022 - 04:30:54


  • HAL Id : hal-01044490, version 1



y. Kasuya, T. Suhara, T. Hayakawa, Philippe Thomas, M. Nogami. Glass Structures and Linea/Nonlinear Optical Properties of Ag2O-doped TeO2 glasses. Key Engineering Materials, Trans Tech Publications, 2014, 617, pp.141-144. ⟨hal-01044490⟩



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