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In Depth Analysis of Photovoltaic Performance of Chlorophyll Derivative-Based “All Solid-State” Dye-Sensitized Solar Cells
Abstract : Chlorophyll a derivatives were integrated in "all solid-state" dye sensitized solar cells (DSSCs) with a mesoporous TiO 2 electrode and 2 ,2 ,7,7-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9-spirobifluorene as the hole-transport material. Despite modest power conversion efficiencies (PCEs) between 0.26% and 0.55% achieved for these chlorin dyes, a systematic investigation was carried out in order to elucidate their main limitations. To provide a comprehensive understanding of the parameters (structure, nature of the anchoring group, adsorption. . .) and their relationship with the PCEs, density functional theory (DFT) calculations, optical and photovoltaic studies and electron paramagnetic resonance analysis exploiting the 4-carboxy-TEMPO spin probe were combined. The recombination kinetics, the frontier molecular orbitals of these DSSCs and the adsorption efficiency onto the TiO 2 surface were found to be the key parameters that govern their photovoltaic response.
Littérature citée [59 références]
https://hal-unilim.archives-ouvertes.fr/hal-02427794
Contributeur : Johann Bouclé <>
Soumis le : lundi 6 juillet 2020 - 15:23:14
Dernière modification le : mercredi 15 septembre 2021 - 11:08:10
Archivage à long terme le : : vendredi 27 novembre 2020 - 11:51:18
Contributeur : Johann Bouclé <>
Soumis le : lundi 6 juillet 2020 - 15:23:14
Dernière modification le : mercredi 15 septembre 2021 - 11:08:10
Archivage à long terme le : : vendredi 27 novembre 2020 - 11:51:18
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molecules-25-00198.pdf
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